Reactions of the Alkylindium(I) Compound In4[C(SiMe3)3]4 with Sulfur and Tellurium: Syntheses of In4S4[C(SiMe3)3]4 and In4Te4[C(SiMe3)3]4 with Indium Chalcogen Heterocubane Structures
β Scribed by Uhl, Werner ;Graupner, Rene ;Pohlmann, Michael ;Pohl, Siegfried ;Saak, Wolfgang
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1996
- Tongue
- English
- Weight
- 418 KB
- Volume
- 129
- Category
- Article
- ISSN
- 0009-2940
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π SIMILAR VOLUMES
Tetraindane(4) / Indium(1) / Co-Co bond I Indium alkyl bridge tetrahedro-Tetrakis[tris(trimethylsilyl)methyl]tetraindane(4) of the oxygen atom of the bridging carbonyl group to the (1) reacts with octacarbonyldicobalt to yield two products, coordinatively unsaturated In atom of a second molecule dep
Structures 1 and 2 are self-complementary but they are also mutually well suited. The hybrid aggregate (1 -2) of 1 and 2 is shown in Scheme 3. The calculated structure of the pear shaped 1 -2 adducts suggests the formation of only six "strong" hydrogen bonds. The two additional bonds are significant
The remaining signals fall in the range of the solvent signals; a silaalkene that can be used for comparison is 9 , in which the C-2 signal lies at 6 = l l 8 . l [ I l l . ## Me ,Si O, , 2,Si Me3 / \ Si=C 9 Me Adarnan tyl 1141 After further irradiation at -110Β°C to -120Β°C the signals of the educt