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Reactions of substituted 5,5-di(R)(Ar)-2-cyclohexenones. I. SN2 and SN2' reactions of 4-bromoisophorone

✍ Scribed by Meislich, H.; Jasne, S.


Book ID
126235475
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
740 KB
Volume
40
Category
Article
ISSN
0022-3263

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✍ Nurhan Horasan-Kishali; Ertan Sahin; Yunus Kara πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 German βš– 218 KB

## Abstract The hydroperoxy endoperoxide **3**, obtained by photooxygenation of isotetralin (= 1,4,5,8‐tetrahydronaphthalene; **1**), was reduced with thiourea, and the resulting intermediate **4** was converted, after acetylation with acetyl chloride, to the interesting, double‐chlorinated acetate