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Reactions of some copper(II) complexes of the Schiff bases of amino-acid esters

✍ Scribed by Gillard, R. D.; Wootton, R.


Book ID
120303103
Publisher
Royal Society of Chemistry
Year
1970
Weight
1018 KB
Category
Article
ISSN
0045-6470

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Solid aquo Cu II complexes of Schiff bases derived from amino acids have been prepared and characterized. Using a pH-stat method, the kinetics of base hydrolysis of the amino acid esters H2NCH2CO2Me.HC1 (GE), (HO)-C6H4CH2(NH2)CO2Me.HC1 (TE), MeS(CH2)2CH(NH2)-CO2Me.HC1 (ME), HSCH2CH(NH2)CO2Et.HC1 (CE

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## Abstract Kinetics of aquation of some Fe(II) Schiff base amino acid complexes was followed spectrophotometrically. The Schiff base ligands were derived from salicylaldehyde and isoleucine, leucine, serine, methionine, tryptophan, or histidine. The reaction was studied in aqueous media, aqua–prop