Reactions of simple hydrocarbon carbanions - II : Stereochemistry of the homogeneous olefin isomerization reaction
โ Scribed by A. Schriesheim; C.A. Rowe Jr.
- Book ID
- 104212550
- Publisher
- Elsevier Science
- Year
- 1962
- Tongue
- French
- Weight
- 170 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
We are reporting that the stereospecificity of cis-2-pentene's metathesis is much greater when the initiator is (C6H5)2C=W(CO)51 than when it is any other previously examined, that this high stereospecificity is similar to that shown by cyclic olefins, 3 and accordingly that no special mechanism is
Stereochemistry of the reactions of methyl-, ethyl-, 2propyl-, and 1 ,I -dimethylethylsulfinyl phenylmethyl carbanions with deuterium oxide and methyl iodide in tetrahydro furan have been studied. The 2-propylsulfinyl phenylmethyl carbanion exerts abnormal behavior in the sense that the alkyl substi