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Reactions of radical cations of acetals: Evidence for unimolecular decomposition

โœ Scribed by I. A. Baranova; V. I. Feldman; V. N. Belevskii

Book ID
112707502
Publisher
Springer
Year
1988
Tongue
English
Weight
488 KB
Volume
126
Category
Article
ISSN
1588-2780

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โœ Richard D. Bowen; Alex G. Harrison ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 471 KB

The reactions of metastable [C,H,,OI+' radical cations produced by ionization of 4-penten-1-01 are reported and discussed. These [CSH,,O1+' species undergo mainly ethyl radical loss, with smaller contributions of methyl radical and water expulsion. \*H-Labelling studies reveal different specificitie