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Reactions of Propargyl Metallic Species Generated by the Addition of Alkynyllithiums to Fischer-Type Carbene Complexes

✍ Scribed by Iwasawa, Nobuharu; Maeyama, Katsuya; Saitou, Masatoshi


Book ID
126297605
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
108 KB
Volume
119
Category
Article
ISSN
0002-7863

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AbstractÐThe anions generated by deprotonation of Fischer-type carbene complexes or by 1,4-addition of lithium enolates to a,bunsaturated complexes are found to act as alkenyl metallic species on iodine oxidation. Various a-methoxy-a,b-unsaturated esters are formed by the treatment of such anions wi