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Reactions of Propargyl Compounds Containing a Cyclobutyl Group Induced by a Ruthenium Complex

✍ Scribed by Yung-Ching Wang; Prof. Dr. Ying-Chih Lin; Yi-Hung Liu

Book ID
115550588
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
486 KB
Volume
7
Category
Article
ISSN
1861-4728

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Reactions of Ruthenium Vinylidene and Acetylide Complexes Containing Trichloromethyl Groups: Preparation of a Cyclobutenonyl Complex by Solid-State Photolysis
✍ Chung-Yeh Wu; Hsien-Hsin Chou; Ying-Chih Lin; Yu Wang; Yi-Hung Liu 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 420 KB

## Abstract Solid‐state route to a cyclobutenone: Ruthenium perchlorocyclobutenonyl complex 2 is obtained by solid‐state photoisomerization of ruthenium trichloroacetyl acetylide complex 1. The four‐membered ring is sufficiently robust that transfer of the intact ligand could be readily achieved in