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Reactions of Photoexcited Aromatic Radical Cations with Polar Solvents †

✍ Scribed by Shkrob, Ilya A.; Sauer, Myran C.; Liu, An Dong; Crowell, Robert A.; Trifunac, Alexander D.


Book ID
126861497
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
200 KB
Volume
102
Category
Article
ISSN
1089-5639

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The time-resolved fluorescence spectra of two pyrylium-ion derivatives have been investigated, in the temperature range 77 to 190 K, a red-shift of the fluorescence spectra of the order of 25-70 nm is observed and assigned to a fast solvent relaxation process. Time-resolved experiments carried out a