Reactions of phosphonium cyclopentadienylide with dienophiles
โ Scribed by Zen-ichi Yoshida; Sigeo Yoneda; Hideaki Hashimoto; Yukichi Murata
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 134 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
It has been shown that the ylide structure (A) predominantly contributes to the phosphonium cyclopentadienylide in the ground state' and the electrophilic substitutions at cyclopentadienyl ring easily take place in the reactions of triphenylphosphonium cyclopentadienylide with various electrophiles.2
๐ SIMILAR VOLUMES
We report briefly the peouliar behaviour toward dienophilee of tosylasoalkenes, whose synthesis has been desoribed (1) reoently. Treatment of tosylarooyolohexene (I) with maleio
## Abstract Reactions of 3โ(1โcyclohexenyl)โ1,2โdimethylindole (1a) and the 1,2โdihydrocarbazole 1b with some carboโ and heterodienophiles are described. Thus, compound 1a reacts to give ene, Michaelโtype, and DielsโAlder adducts, depending on the dienophile and reaction conditions. The 3โvinylindo