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Reactions of phosphines with acetylenes. Part 18. The mechanism of formation of 1,2-alkylidenediphosphoranes

โœ Scribed by Tebby, John C.; Wilson, Ian F.; Griffiths, D. Vaughan

Book ID
121411433
Publisher
Royal Society of Chemistry
Year
1979
Weight
336 KB
Category
Article
ISSN
1472-7781

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The formation of C3H3 (propynyl) radical
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โœ Carlos E. Canosa-Mas; Mark Ellis; H. Monty Frey; Robin Walsh ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 350 KB

Results obtained from the photolysis of ketene with acetylene strongly support the formation of C,H, radicals in the title reaction. Stationary state studies are interpreted in terms of the reaction C,H: 5 C,H, + H with a rate constant (log8 s '1 which is compared to RRKM predictions. In pulsed lase