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Reactions of phenylthiotrimethylsilylmethyllithium: Preparation of α-phenylthioketones and additions to 2-cyclohexen-1-one

✍ Scribed by David J Ager

Book ID
104241752
Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
201 KB
Volume
22
Category
Article
ISSN
0040-4039

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✦ Synopsis

Phenylthiotrimethylsilylmethyllithium(l) was reacted with a variety of electrophiles, including some containing two functional groups. o(-Phenylthioketones were obtained from the reaction with esters. The anion(l) underwent either 1,2-or l,&addition,depending on the conditions used, with 2-cyclohexen-l-one.

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