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Reactions of Perfluoroalkyl Nitriles. V. Synthesis of Perfluoroacyl Imidates 1

✍ Scribed by Brown, Henry C.; Wetzel, Charles R.

Book ID
120014721
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
676 KB
Volume
30
Category
Article
ISSN
0022-3263

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## Abstract Diethyl (1‐cyanoethyl) phosphorate 1 was reacted with __n__‐butyl‐lithium in tetrahydrofuran (THF) at ‐ 78 Β°C and the resulting carbanion 2 reacted with perfluoroalkanoic add anhydride to afford perfluoroacylated phosphorate 3. Without isolation 3 was attacked by Grignard reagents givin