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Reactions of organic anions. XII. Vinylation of phenylacetonitrile derivatives

✍ Scribed by M. Ma̧kosza

Publisher
Elsevier Science
Year
1966
Tongue
French
Weight
160 KB
Volume
7
Category
Article
ISSN
0040-4039

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✦ Synopsis

The direct 0-, S-, and N-vlnylation,animportant reaction, proceeds in the preaenoe of basic catalysts, end is usually considered ae a nucleophilic addition to the acetylenic bond /l/. However, only a few examples of direct C-vtiylation are known. Karpukhin /2/ prepared 9-vlnylfluorene from fluorene end acetylene at 200' under 30 atm. in the presence

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