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Reactions of O-silylated enolates with allylsilane bifunctional [4+2] and [5+2] annulating reagents

✍ Scribed by Thomas V. Lee; Raymond J. Boucher; John R. Porter; Caroline J.M. Rockell

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 433 KB
Volume: 45
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)89115-8

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✦ Synopsis

Stunmary: The reactions of the two aliylsilane-acetals (8) and (9) with various 0-silylated enolates is described. This has resulted in a new route to fused carbocyclic six and seven-membered rings in a one-pot reaction by use of a chemospecific allylsilane based bijknctional annulating reagent.

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