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Reactions of NNOH+ and HNNO+ ions with CH4 and NO

✍ Scribed by Eldon E. Ferguson

Book ID
103027229
Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
387 KB
Volume
156
Category
Article
ISSN
0009-2614

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✦ Synopsis

measurements for the reactions of N20H+ with CH4 and NO are interpreted. Two species of different reactivity are established to be the isomers NNOH+ and HNNO+, the latter lying energetically above the more stable NNOW by 6 & 1.5 kcal mol-'. This is in excellent agreement with recent theoretical calculations. Both ions react with NO to produce NO++OH+Nz. N,OH+ reacts by a simple dissociative charge transfer, the unstable neutral product breaks at its weakest bond, the only exoergic reaction path. The less stable, more energetic HNNO+ ion reacts with NO in a more complicated manner.

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