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Reactions of nitrones with di- and tetrahydropyrans

✍ Scribed by Kh. F. Sagitdinova; U. G. Ibatullin; Z. R. Gallyamova; G. A. Rakhmatullina; N. A. Akmanova; M. G. Safarov

Book ID
104783344
Publisher
Springer US
Year
1990
Tongue
English
Weight
306 KB
Volume
26
Category
Article
ISSN
0009-3122

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✦ Synopsis

N-(Benzylidene)-and N-(2-phenylamino-2-oxoethylidene)aniline N-oxides add stereospecifically to the double bond in 4-methylene-and 4-acryloylamino-4-methyltetrahydropyrans to give substituted isoxazolidines. The use of 4-methyl-5-arylamino-and 4-arylaminomethyl-5,6-dihydro-2H-pyrans for the synthesis of novel N-oxides has given tricyclic adducts resulting from intramolecular cyclization of the required compounds.

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