Reactions of Nitroarenes with Secondary and Tertiary Carbanions Bearing Both a Leaving Group and Electron-Withdrawing Group: An Approach to Dihydronaphth[2,1-c]isoxazole N-Oxides and Dihydroisoxazolo[4,3-f]quinoline N-Oxides.

Reactions of nitroarenes with secondary

Reactions of nitroarenes with secondary and tertiary carbanions bearing both a leaving group and electron-withdrawing group: An approach to dihydronaphth[2,1-c]isoxazole N-oxides and dihydroisoxazolo[4,3-f]quinoline N-oxides

✍ Hiroshi Maruoka; Yukihiko Tomioka 📂 Article 📅 2003 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 94 KB

## Abstract 2‐Nitronaphthalene **(1)** and 6‐nitroquinoline **(2)** underwent direct cyclocondensation with secondary and tertiary carbanions derived from a methylene and methine group bearing both a leaving group and electron‐withdrawing group (__e.g.__, methyl chloroacetate, ethyl chloroacetate,