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Reactions of nitrenes with strained olefins. Preparation of dimethyl-N-phthalimidyl-5-azabieyclo[2.1.0]pentane-1,4-dicarboxylate

✍ Scribed by G. Richard Meyer; Jerome Stavinoha Jr.


Book ID
112123593
Publisher
Journal of Heterocyclic Chemistry
Year
1975
Tongue
English
Weight
62 KB
Volume
12
Category
Article
ISSN
0022-152X

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✍ María I. García Trimiño; Arturo Macías Hermán Vélez Cabrera Castro; Arístides Ro 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 594 KB

The redction of N,N -dimethyl-2-nitroethene-I,l-diamine (8) with cc,j-unsaturdted dcyl ISOthiOCydndteS 9 dffords 3,3-diamino-2-nitroacrylthioamides 10 (Scheme 2) in moderate-to-good yields Cyclization of 10 under acidic conditions gives 1,3-thiazin-4-one derivatives of type 11 Oxiddtive cyclization