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Reactions of N-Bromosuccinimide. II1,2

โœ Scribed by Barnes, Roderick A.; Buckwalter, Geoffrey R.

Book ID
115474263
Publisher
American Chemical Society
Year
1951
Tongue
English
Weight
520 KB
Volume
73
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

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The reaction of 2-methylnorborn-2-ene with N-bromosuccinimide produced exo-3bromo-2-methylenenorbornane and 2-methyl-3-bromonortricyclene in a 3 : 1 ratio. No 2-bromomethyl-norborn-2-ene was found. Most of the unreacted olefin was found to be isomerized to 2methylenenorbornane. The hydrolysis of 2-

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## Abstract The reaction of 2โ€methylenenorbornane with Nโ€bromosuccinimide produced a mixture of six monobromides in an overall yield of about 60%. By irradiation in the presence of benzoyl peroxide __exo__โ€ and __endo__โ€3โ€bromoโ€2โ€methylenenorbornanes, 2โ€bromomethylnorbornโ€2โ€ene, __Z__โ€ and __E__โ€2โ€