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Reactions of methyliron(1+) (MeFe+) and methylcobalt(1+) (MeCo+) with aliphatic alkenes and alkynes in the gas phase

โœ Scribed by Jacobson, D. B.; Freiser, B. S.


Book ID
127158317
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
987 KB
Volume
107
Category
Article
ISSN
0002-7863

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Rate constants for the gas-phase reactio
โœ Eric Grosjean; Daniel Grosjean ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 521 KB

The gas-phase reaction of ozone with eight alkenes including six I ,I-disubstituted alkenes has been investigated at ambient T (285-298 K) and p = 1 atrn. of air. The reaction rate constants are, in units of lo-" cm3 molecule-' s ~' . 9 50 5 1.23 for 3-methyl-I-butene. 13 I ? I 8 for 2-methyl-I-pent