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Reactions of methyl 1-acetylenyl-9,10-anthraquinone-2-carboxylates with hydrazine

โœ Scribed by I. D. Ivanchikova; R. N. Myasnikova; M. S. Shvartsberg

Publisher
Springer
Year
1998
Tongue
English
Weight
404 KB
Volume
47
Category
Article
ISSN
1573-9171

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## Abstract The synthesis of 9,10โ€dimethoxyโ€2โ€methylโ€1,4โ€anthraquinone, an unusual quinone, was achieved in five steps from __p__โ€benzoquinone. A Kochiโ€“Anderson radical methylation features as the key step in the synthesis. The chemistry of a cyclopropaโ€1,4โ€anthracenedione is also described. (ยฉ Wil