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Reactions of metal phosphides and arsenides. Adamantene from 1,2-dibromo- and 1,2-diiodoadamantane

✍ Scribed by Donal G. Gillespie; Brian J. Walker

Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
193 KB
Volume
18
Category
Article
ISSN
0040-4039

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✦ Synopsis

Under circumstances where nucleophilic attack on carbon is unfavourable, metal phosphides act as adequate dehalogenating agents to give acetylenes from vinyl halides 2 .and dehydrobenzene from 1,2-dihalobenzenes 3 . In view of this the generation of anti-Bredt olefins by a similar reaction of the appropriate dihalide seemed likely.

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