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Reactions of metal carbonyl derivatives. Part XV. Oxidation studies of some ?-cyclopentadienyl bridging sulphido- and phosphino-derivatives of iron

โœ Scribed by de Beer, Jacob A.; Haines, Raymond J.; Greatrex, Robert; van Wyk, Jan A.


Book ID
120288642
Publisher
The Royal Society of Chemistry
Year
1973
Tongue
English
Weight
862 KB
Volume
21
Category
Article
ISSN
1472-7773

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The organothio-bridged derivatives of ir
โœ G. Natile; L. Maresca; G. Borb ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 567 KB

The anti-syn interconversion rate of (p-Buts),-Fe,(CO), is about one thousand times faster than that of the other alkyl and aryl derivatives and becomes fast in the NMR time scale at temperatures above 90 'C. The coalescence temperature of the But signals is lowered by substitution of a carbonyl gro