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Reactions of magnesium hydrides. 2. Stereoselective reduction of cyclic and bicyclic ketones by hydridomagnesium alkoxides

✍ Scribed by Ashby, E. C.; Lin, J. J.; Goel, A. B.

Book ID: 126188721
Publisher: American Chemical Society
Year: 1978
Tongue: English
Weight: 418 KB
Volume: 43
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00402a018

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5.00 (q, J = 6.5, CHCH,); arom. H's hidden. I3C-NMR (C6D6): 24.7 (CH,); 69.5 ( C H C H ? ) ; 119.8 (C(5')); 121.7 (C(3')); 136.4 (C(4')); 148.4 (C(6')); C(2') not observed. ## ') An alternative mechanism, that cannot be excluded, involves the intermediacy of a metallo-ester, formed by a reversibl