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Reactions of Laser-Ablated Scandium Atoms with Dioxygen. Infrared Spectra of ScO, OScO, (O 2 )ScO, (ScO) 2 , and Sc(O 2 ) 2 in Solid Argon

โœ Scribed by Chertihin, George V.; Andrews, Lester; Rosi, Marzio; Bauschlicher, Charles W.


Book ID
118742261
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
182 KB
Volume
101
Category
Article
ISSN
1089-5639

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A translationally fast pulsed beam of scandium atoms, ions, and scandium monoxide is produced by laser vaporization using the second harmonic (I= 532 nm) of a Nd: YAG laser. Laser power densities range from 1.1 x 1O'to 9.5 x 10s W cm-\*, resulting in beams with kinetic energies up to 30 eV. The kine