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Reactions of Isocyanatophosphoryl Difluoride with π-Abundant Nitrogen Heterocycles and Carbonyl Compounds.

✍ Scribed by R. V. Smaliy; A. A. Chaikovskaya; A. M. Pinchuk


Publisher
John Wiley and Sons
Year
2006
Weight
18 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Reactions of Pentafulvene Complexes of T
✍ Jörg Stroot; Rüdiger Beckhaus; Wolfgang Saak; Detlev Haase; Arne Lützen 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 287 KB 👁 2 views

The compound Cp\*Ti[η 6 -C 5 H 4 C(H)(tBu)]Cl (1) reacts with ketones, aldehydes, and esters to give σ,π-chelate complexes with Cp~O ligands through insertion of the carbonyl group into the Ti-C(H)(tBu) bond. Starting from diastereomerically pure 1, the reaction with symmetric ketones R 2 CO led to