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Reactions of Ion-Pair Intermediates of Solvolysis

✍ Scribed by Yutaka Tsuji; John P. Richard

Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

Mechanisms of elimination and substituti
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✍ Qingshui Meng; Baoan Du; Alf Thibblin πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 78 KB

The reactions of 4-(4'-nitrophenyl)-4-X-butan-2-one (1-X; X = Cl, OTs) with added bases/nucleophiles exhibit second-order kinetics. These substitution and elimination reactions are concluded to be of concerted S N 2 type and irreversible E1cB type, respectively. The spontaneous formation of alkene f