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Reactions of hydroxymethyl derivatives of uric acid with oxiranes: Recognition of mechanism based on kinetic studies

✍ Scribed by Jacek Lubczak

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
197 KB
Volume
38
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

Kinetic and mechanistic studies on the reaction between 1 equivalent of 1,3,7,9‐tetrakis(hydroxymethyl) ureate with 1 equivalent of oxirane (ethylene oxide or propylene oxide) are presented. This study led to recognition of the mechanism of reaction. It has been found that during the reaction the release of formaldehyde from hydroxymethyl groups blocked with oxirane occurs. The formaldehyde is consequently bound to the end of etherol chain. Owing to this rearrangement, the amount of formaldehyde remains constant during the process. Β© 2006 Wiley Periodicals, Inc. Int J Chem Kinet 38: 345–350, 2006

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