Reactions of hydroxyl and nitrogen trioxide radicals with phenol, cresols, and 2-nitrophenol at 296 .+-. 2 K
โ Scribed by Atkinson, Roger; Aschmann, Sara M.; Arey, Janet
- Book ID
- 124160311
- Publisher
- American Chemical Society
- Year
- 1992
- Tongue
- English
- Weight
- 908 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0013-936X
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Using a relative rate technique, rate constants for the gas-phase reactions of the OH radical with the three cresols and the six dimethylphenols have been determined a t 296 t 2 K and atmospheric pressure. The rate constants for the cresols, which range from 4.3 x lo-" cm3 molecule-' s-' to 6.8 x lo
Reaction of o-and p-cresol, the xylenols, and 2-naphthol with nitrogen dioxide gives nitrocyclohexadienones and nitrophenols. Secondary nitrodienones, the keto tautomers of the nitrophenols, have been observed in several cases and are intermediates in the formation of the nitrophenols. 2,4,6\_Trisub