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Reactions of Halomethanes with γ-Alumina Surfaces. 1. An Infrared Spectroscopic Study

✍ Scribed by Dai, Qing; Robinson, Gary N.; Freedman, Andrew

Book ID
127058569
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
213 KB
Volume
101
Category
Article
ISSN
0022-3654

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Infrared spectra of Cr(CO)6 adsorbed at different surface centers on gamma-alumina were investigated. The spectra of the probe complex revealed the existence of three types of strong Lewis centers and that of physisorbed Cr(CO)6. In the case of the physisorbed complex Oh symmetry was widely conserve