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Reactions of halodifluorophosphines with silver salts

✍ Scribed by Flaskerud, Gerald G.; Pullen, Kent E.; Shreeve, Jean'ne M.


Book ID
126294990
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
365 KB
Volume
8
Category
Article
ISSN
0020-1669

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Phosphenium cations / Silver complexes / 31P,109Ag NMR shift correlation Reaction of bis(diisopropy1amino)phosphenium triflate (l[CF3S03]) with silver salts AgY [Y-= CF3C0, (Za), CF:{-SO, (2b), CH3C0y (2c)l affords neutral complexes [[(iPr,N),(Y)P) Ag(OS02CF3)] (3a -c). While 3a, c are stable up to