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Reactions of haloarenes, haloheteroarenes and dihalobenzenes with triphenylstannyl anions in DMSO and acetonitrile

✍ Scribed by Marı́a T. Lockhart; Alicia B. Chopa; Roberto A. Rossi


Book ID
108354759
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
118 KB
Volume
582
Category
Article
ISSN
0022-328X

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Reactions of Haloarenes with Thiolate An
✍ Stephen D. Pastor 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 German ⚖ 533 KB

The reaction of the hromo-substituted naphthalene 1 with the alkanethiolate anions 2a-b and arenethiolate 2c in tetraglyme gave the corresponding 1 -naphthyl thio-ethers 3a\*. Thio-ethers 3a-e were oxidized to the corresponding sulfones 4a\* with m-chloroperoxybenzoic acid. The reaction of the dichl