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Reactions of glyoxal-derived iminium ions with unsaturated silyl and silyloxy reagents

✍ Scribed by Claude Agami; Dominique Bihan; Catherine Puchot-Kadouri

Book ID
107857882
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
487 KB
Volume
52
Category
Article
ISSN
0040-4020

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✍ Seiji Suga; Masayuki Okajima; Jun-ichi Yoshida πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 74 KB

We have developed an efficient direct oxidative a-alkylation and -arylation of carbamates based on the 'cation pool' method. Grignard reagents, organozinc compounds, and organoaluminum compounds are effective as carbon nucleophiles toward iminium cation pools generated by low temperature electrolysi