## Abstract The nature of interaction of Co(III) complexes such as Co(III)EDTA and Co(III)NTA with transient adducts of thymine such as TOH^Λ^, T^Λβ^, and TH^Λ^ formed in the gamma radiolysis of thymine were studied. The study shows that TOH radicals do not undergo electron transfer reaction with C
Reactions of free radicals with monoethyldichlorochromium(III) tris(tetrahydrofuranate)
β Scribed by Reiner Sustmann; Rudolf Altevogt
- Book ID
- 104243565
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 117 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
The kinetics and absolute rate constants for the free-radical chain reaction of tri-nbutyltin hydride with di-t-butyl disulfide have been measured in cyclohexane at 30". The rate controlling step for chain propagation involves the cleavage of the disulfide bond by an attacking tributyltin radical. T
## Abstract Rate constants for the triβ__n__βbutyltin radical (**Sn Β·**) induced decomposition of a number of peroxides have been measured in benzene at 10Β°C. The values range from βΌ100 __M__^β1^ sec^β1^ for diβ__t__βbutyl peroxide to 2.6 Γ 10^7^ __M__^β1^ sec^β1^ for diβ__t__βbutyl diperoxyisophth
i-C4HgON0 was photolyzed with 366-nm radiation at -8, 23, 55, 88, and 120Β°C in a static system in the presence of NO, O,, and N2. The quantum yield of i-C,H7CH0, @{i-C3H7CHO}, was measured as a function of reaction conditions. The primary photochemical act is and it proceeds with a quantum yield &