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Reactions of formic acid. 1. The iridium-catalyzed synthesis of acetic acid from methyl formate

✍ Scribed by Pruett, Roy L.; Kacmarcik, Raymond T.

Book ID
120290766
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
781 KB
Volume
1
Category
Article
ISSN
0276-7333

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πŸ“œ SIMILAR VOLUMES

On the rhodium catalyzed formation of ac
On the rhodium catalyzed formation of acetic acid from methyl formate β€” comparison with the rhodium catalyzed formation of acetic acid by direct carbonylation of methanol
✍ G. Bub; H.-U. HΓΆg πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 662 KB

In presence of the homogenous Rh/Cr/I catalyst system methyl formate can be isomerized to acetic acid under CO-pressure with high conversion rates and excellent selectivity. This catalyst system has never been applied before for this reaction.