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Reactions of excited triplet diphenylcarbene studied with picosecond lasers

✍ Scribed by Wang, Y.; Sitzmann, E. V.; Novak, F.; Dupuy, C.; Eisenthal, K. B.


Book ID
127318489
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
305 KB
Volume
104
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES


Picosecond laser studies of the charge-t
✍ E.V. Sitzmann; J. Langan; K.B. Eisenthal πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 English βš– 509 KB

C\ idence of a one-electron transfer process in a carbene reaction has been observed for the first time. The exunple is the quench;ng of the photoescited triplet state of diphenylcarbene (3\*DPC) by electron donors. Measurement of the fluorescence lifetime as a function of donor concentration yielde

Picosecond laser studies of the effects
✍ E.V. Sitzmann; J.G. Langan; K.B. Eisenthal πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 English βš– 523 KB

Picosecond laser induced fluorescence measurements provide for the first time the direct meanrrement of the intramolccular and intermolecular energy decay dynamics of singlet diphenylcarbene (' DPC) in the presence of reactive molecules. As exemplified by the reaction of ' DPC with alcohols it is fo