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Reactions of ethyl β-methoxycrotonate with some α,β-unsaturated carbonyl compounds. Synthesis of 6-aroyl-5-aryl-3-methoxycyclohex-2-enones

✍ Scribed by Mowafak Y. Shandala; Mikdad T. Ayoub; Ahmad A. Kareem


Book ID
112127689
Publisher
Journal of Heterocyclic Chemistry
Year
1984
Tongue
English
Weight
158 KB
Volume
21
Category
Article
ISSN
0022-152X

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✍ Hiroshi Maruoka; Motoyoshi Yamazaki; Yukihiko Tomioka 📂 Article 📅 2002 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 60 KB

## Abstract The reactions of 2‐amino‐4,5‐dihydro‐3‐furancarbonitriles **1a‐d** with α,β‐unsaturated carbonyl compounds in the presence of sodium ethoxide (0.1 equivalent) gave the corresponding Michael adducts **2a‐d**, **3a‐d** and **4a‐d.** Compounds **2a‐d** and **3a‐c** reacted with sodium alko