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Reactions of donor-substituted furans with electrophilic ethylenes

โœ Scribed by Grzegorz Mloston; Rolf Huisgen


Book ID
112131030
Publisher
Journal of Heterocyclic Chemistry
Year
1994
Tongue
English
Weight
315 KB
Volume
31
Category
Article
ISSN
0022-152X

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Reactions of Di(tert-butyl)diazomethane
โœ Rolf Huisgen; Peter Pรถchlauer; Grzegorz Mlostoล„; Kurt Polborn ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 187 KB

## Abstract Di(__tertโ€__butyl)diazomethane (**4**) is a nucleophilic 1,3โ€dipole with strong steric hindrance at one terminus. In its reaction with 2,3โ€bis(trifluoromethyl)fumaronitrile ((__E__)โ€**BTE**), a highly electrophilic tetraโ€acceptorโ€substituted ethene, an iminoโ€substituted cyclopentene **9