Reactions of dicarbonyl compounds with dimethyl .beta.-ketoglutarate: II. Simple synthesis of compounds of the [10.3.3]- and [6.3.3]-propellane series
โ Scribed by Yang, Daisy.; Cook, James M.
- Book ID
- 126061520
- Publisher
- American Chemical Society
- Year
- 1976
- Tongue
- English
- Weight
- 737 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
The influence of steric factors on the synthesis of substituted bicyclo[3.3.01octane-3,7 drones via the condensation of 1,2-dicarbonyl compounds with dimethyl 3-ketoglutarate 2 is described. Recently Bertz reported a new approach to synthetic analysis la,lb which employs graph theory and informatio
The steric and electronic influences of.subs.ituen 'j attached to he arbonyl system on the success of the reaction o 1 1,2-$lketones with $imethyl 3-ketoglutarate 2. have been examined. It is clear from the reaction of 2 with benzil, thienil. furil. and phenanthrenequinone 1. respectively, coupled