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Reactions of diazoalkanes with unsaturated compounds 15. Catalytic reactions of unsaturated carbonyl compounds and their derivatives with diazomethane

✍ Scribed by M. D. Khanova; R. M. Sultanova; S. S. Zlotskii; V. A. Dokichev; Yu. V. Tomilov


Publisher
Springer
Year
2005
Tongue
English
Weight
364 KB
Volume
54
Category
Article
ISSN
1573-9171

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## Abstract Except from 1,4,9,10‐anthracenetetrols, 9,10‐anthrahydroquinones (derived from the quinones **5a** and **18**– **21**) react with unhindered Michael acceptors such as acrylate, acrylonitrile, acrylaldehyde, and methyl vinyl ketone with addition at C‐9 or C‐10 to yield anthrones. The dir