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Reactions of diazoacetates with phosphate triesters and thiophosphate triester: and intermediacy formation

✍ Scribed by Konstantin A Popov; Alexander M Polozov; Sergei V Tcherezov


Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
202 KB
Volume
38
Category
Article
ISSN
0040-4039

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## Abstract The reactions of diethyl 4‐nitrophenyl phosphate (**1**) with a series of nucleophiles: phenoxides, secondary alicyclic (SA) amines, and pyridines are subjected to a kinetic study. Under excess of nucleophile, all the reactions obey pseudo‐first‐order kinetics and are first order in the