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Reactions of chromium(III) complexes with ferricyanide. Magnetism of K2[Cr(salen)(H2O)][Fe(CN)6]·H2O and the crystal structure of [trans-Cr(tn)2Cl2]3[Fe(CN)6]·6H2O [salen2− = N,N′-ethylenebis(salicylideneaminato) dianion, tn = 1,3-diaminopropane]

✍ Scribed by Hui-Zhong Kou; Dong-Zhao Gao; Wie-Ming Bu; Yu-Guo Fan; Dai-Zheng Liao; Peng Cheng; Zong-Hui Jiang; Shi-Ping Yan; Geng-Lin Wang; Tian-Jian Li; Jin-Kui Tang


Book ID
110297139
Publisher
Springer
Year
2001
Tongue
English
Weight
219 KB
Volume
26
Category
Article
ISSN
0340-4285

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Tetrapropylammonium and -phosphonium ions, nPr 4 E ؉ , react readily with the polymeric super-Prussian blue derivatives [(Me 3 Sn) 3 M(CN) 6 ] (M ‫؍‬ Co, Ir), which are built up of in5nite [ +M+CN+Sn+NC] + chains, a4ording the dimorphic supramolecular assembly [(nPr 4 E)(Me 3 Sn) 2 M(CN) 6 ' 2H 2 O]