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Reactions of chloromethyl aryl sulfones carbanions with anthraquinone derivatives

✍ Scribed by Mieczysz.shtsls;law Ma̧kosza; Shamil Nizamov; Zofia Urbańczyk-Lipkowska


Book ID
108378994
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
633 KB
Volume
54
Category
Article
ISSN
0040-4020

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Reactions of the carbanion of chlorometh
✍ Mieczysław Mąkosza; Natalia Urbańska; Alexey A. Chesnokov 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 159 KB

Addition of the carbanion of chloromethyl methyl sulfone to aldehydes and ketones proceeds faster than its degradation via the Ramberg-Baecklund reaction. Chlorohydrins and oxiranes produced from aldehydes treated with an excess of base undergo the Ramberg-Baecklund reaction giving allylic alcohols,