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Reactions of cationic vinylidene complexes [Fe{=C=C(R1)R2}(η-C5H5)(dppm)]+[dppm = bis(diphenylphosphino)methane] with nucleophiles: stereoselective synthesis and crystal structure of the alkenyl complex (E)-[Fe{C(H)=C(Me)Ph}(η-C5H5)(dppm)]

✍ Scribed by M.Pilar Gamasa; José Gimeno; Elena Lastra; Maurizio Lanfranchi; Antonio Tiripicchio


Book ID
107812341
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
357 KB
Volume
430
Category
Article
ISSN
0022-328X

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Reactivity of the Inversely Polarised Ar
✍ Lothar Weber; Philipp Bayer; Gabriel Noveski; Hans-Georg Stammler; Beate Neumann 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 177 KB

## Abstract The reaction of the vinylidene complexes [(C~5~H~5~)(CO)(NO)W=C=C(H)R] (10a: R = __t__Bu; 10b: R = Ph) with the arsaalkene __t__BuC(O)–As=C(NMe~2~)~2~ (11) afforded the novel η^2^‐1‐arsaallene complexes [η^2^‐{__t__BuC(O)–As=C=C(H)R}W(CO)(NO)C~5~H~5~] (13: R = __t__Bu; 15: R = Ph). Simi