Reactions of carbonyl compounds with tervalent phosphorus reagents. Part 12. Aromatic aldehydes with bromophosphines and phosphorus tri-iodide
β Scribed by Michie, Jacqui K.; Miller, J. Allen; Nunn, M. John; Stewart, Denis
- Book ID
- 121335720
- Publisher
- Royal Society of Chemistry
- Year
- 1981
- Weight
- 809 KB
- Category
- Article
- ISSN
- 1472-7781
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π SIMILAR VOLUMES
Tetrasulfurtetranitride, S f l , reacts with (2-pyridylamino)-diphenylphosphine in MeCN at room temperature to form the cyclotrithiazene (NCjHflH)-Ph,PN-S3N3 (1) in good yield. By contrast, the cyclophosphathiazeries Ph,PS2N3 (2) and l,5(Ph,P)fi2N4 (3) are isolated ;from the same reaction mixture un
Tris(2,6-diphenylphenoxide) (ATPH). -1,6-Addition of silyllithium reagents to aromatic carbonyl compound ATPH complex and following enolate capture with an appropriate electrophilic reagent leads to functionalized allylsilanes shown in the scheme. In the reaction of (I), aromatic silylated products