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Reactions of carbon tetrachloride with unsaturated compounds in presence of dicyclohexyl peroxydicarbonate or oxidation-reduction systems

โœ Scribed by E. Ts. Chukovskaya; A. A. Kamyshova; R. Kh. Freidlina

Book ID
112420285
Publisher
Springer
Year
1965
Tongue
English
Weight
344 KB
Volume
14
Category
Article
ISSN
1573-9171

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Absmcf: 1,2-Dihalocyclop%enes on reaction with alkali metals and chlomlrimethylsilane in hydmcarbon or ether solvents produce silylatcd I-pentynes by ring opening. Sodium metal and hydrwarbon solvents favour the cleavage most. Different mechanistic aspxts are considered.