## Abstract Review: 247 refs.
Reactions of C3 with alkenes, alkynes and allenes
β Scribed by H.H. Nelson; Louise Pasternack; John R. Eyler; J.R. McDonald
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 553 KB
- Volume
- 60
- Category
- Article
- ISSN
- 0301-0104
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## Abstract Transitionβmetalβcatalyzed coupling of two different Cο£ΏC Ο components through a metallacycle intermediate is a highly atom economical method to construct Cο£ΏC bonds in organic synthesis. The metalβcatalyzed coupling of an alkene and alkyne generally gives an Alderβene or reductive coupli
The base mediated reactions of alkenyl alkyl ethers (cf. (I), (III), ( V)) as well as ketene acetals (VII) with phosphorus trihalides result in the unprecedented electrophilic substitution of a vinylic hydrogen by a dihalogenophosphine group furnishing (alkoxyalkenyl) dihalogenophosphines in good yi