As part of a study of organosulphur compounds in heavy oil sands, the interaction of thiophene (1) and tetrahydrothiophene (10) with aqueous solutions of Group VIIIB metal species at 20&24o"C has been \_ investigated. Thiophene was the more reactive and the greatest degree of reaction was observed
โฆ LIBER โฆ
Reactions of benzo[b]thiophene with aqueous metal species: their influence on the production and processing of heavy oils
โ Scribed by Clark, Peter D.; Lesage, Kevin L.; Tsang, Gerald T.; Hyne, James B.
- Book ID
- 126435868
- Publisher
- American Chemical Society
- Year
- 1988
- Tongue
- English
- Weight
- 522 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0887-0624
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The title reaction, carried out in DMF in the presence of triethylamine or potassium carbonate, has furnished the 'expected' 3-amino-2-nitrobenzo[b]thiophenes 2o together with the 'unexpected' 2-amino-3-nitrobenzo[b]thiophenes 3o, thus recalling the situation observed with other weak nucleophiles in