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Reactions of azirines with N-bromosuccinimide

✍ Scribed by Howard Alper; Martin Laplante

Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
170 KB
Volume
34
Category
Article
ISSN
0040-4020

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## Abstract The reaction of 2‐methylenenorbornane with N‐bromosuccinimide produced a mixture of six monobromides in an overall yield of about 60%. By irradiation in the presence of benzoyl peroxide __exo__‐ and __endo__‐3‐bromo‐2‐methylenenorbornanes, 2‐bromomethylnorborn‐2‐ene, __Z__‐ and __E__‐2‐

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✍ C. W. Jefford; W. Wojnarowski 📂 Article 📅 1970 🏛 John Wiley and Sons 🌐 German ⚖ 654 KB

The reaction of 2-methylnorborn-2-ene with N-bromosuccinimide produced exo-3bromo-2-methylenenorbornane and 2-methyl-3-bromonortricyclene in a 3 : 1 ratio. No 2-bromomethyl-norborn-2-ene was found. Most of the unreacted olefin was found to be isomerized to 2methylenenorbornane. The hydrolysis of 2-