Reactions of azides with α-ester phosphorus ylids
✍ Scribed by G. L'Abbé; P. Ykman; G. Smets
- Book ID
- 111714356
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 366 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4020
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📜 SIMILAR VOLUMES
During the course of our investigation of the synthesis of oic-triasoles by reacting a-keto-and a-ester phosphorus ylides with acyl asides and ethyl asidoformate (1 + 2 + z), we found that the N-l substituted triasoles,isomerised to the N-2 substituted triasoles (1 + A) under the basic reaction cond
Phosphorus ylids find great utility in synthesis where the best known reactions such as the Wittig and variants thereof are used for the construction of carbon-carbon bonds.' We now report a new, sinple reaction of ~tho~carbonylalkylidenephosphoranes with singlet oxygen to